Antimonide bromide

Antimonide bromides or bromide antimonides are compounds containing anions composed of bromide (Br⁻) and antimonide (Sb³⁻). They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the antimonide chlorides, antimonide iodides, arsenide chlorides, arsenide bromides, arsenide iodides, phosphide chlorides, phosphide bromides, and phosphide iodides.^[1] The bromoantimonates have antimony in positive oxidation states.

The antimony can be linked into chains, in which case it has a formal oxidation state of −1. Alternately it can be in pairs as Sb₂, with an oxidation state of −2 for each atom.^[2]

Many of these compounds are clathrates, whereby there are two interpenetrating structures that are only weakly bound to each other by van der Waals force.

List

formula	system	space group	unit cell Å	volume	density	comment	ref
Ge₃₈Sb₈Br₈	cubic	P43n	a=10.7893	756.5		clathrate	^[3]
Cd₂SbBr₂	monoclinic	P2₁	a=8.244 b=9.920 c=8.492 β=116.80			Contains Sb-Sb⁴⁻	^[4]
Hg₆Sb₅Br₇	cubic	Pa3	a=13.003 Z=4	2198.6	7.165	black	^[2]
Hg₇Sb₄Br₆	cubic	Pa3	a = 12.9940 Z = 4			black	^[5]^[6]
Hg₁₉Sb₁₀Br₁₈							^[7]
(Hg₁₃Sb₈)(ZnBr₄)₄	orthorhombic	Pnma	a=27.120 b=12.965 c=14.579 Z=4	4126	6.637		^[8]
Sb₂Hg₃GaBr₄	orthorhombic	Pnma	a = 13.7549, b = 12.690, c = 14.7819, Z = 8			red	^[9]
(InBr₆)Br	cubic	Pa3	a = 12.8542 Z=4	2123.91	7.395	dark red	^[10]
Hg₁₂Sb₆(Br_5.186I_6.814)	triclinic	P1	a = 7.791 b = 11.680 c = 12.404 α = 112.76° β = 99.99° γ = 102.04° Z=1	976,7	7.477	orange; band gap 2.1 eV	^[7]
Hg₃Sb₂TlBr₃	orthorhombic	Pbcm	a = 6.610, b = 13.112 c = 13.071			black	^[11]
Hg₆Sb₄BiBr₇	cubic	Pa3	a=12.998 Z=4	2196.0	7.437	black	^[2]

References

^ Shevelkov, A. V.; Shatruk, M. M. (2001). "". Russian Chemical Bulletin. 50 (3): 337–352. doi:10.1023/a:1011351532249. S2CID 94548971.
^ ^a ^b ^c Beck, Johannes; Hedderich, Sylvia; Neisel, Udo (November 2000). "Synthesis and Crystal Structures of Hg₆Sb₅Br₇, Hg₆As₄BiCl₇, and Hg₆Sb₄BiBr₇, Built of a Polycationic Mercury-Pnictide Framework with Trapped Anions". Journal of Solid State Chemistry. 154 (2): 350–355. Bibcode:2000JSSCh.154..350B. doi:10.1006/jssc.2000.8794.
^ Menke, Heinz; von Schnering, Hans Georg (January 1973). "Die Käfigverbindungen Ge38A8X8mit A = P, As. Sb und X = Cl, Br, J". Zeitschrift für anorganische und allgemeine Chemie (in German). 395 (2–3): 223–238. doi:10.1002/zaac.19733950211. ISSN 0044-2313.
^ L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (1999). "Synthesis and crystal structure of Cd₂SbBr₂". Koordinatsionnaya Khimiya (in Russian). 25 (11). ISSN 0132-344X.
^ Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (May 1992). "The crystal structure of Hg₇Sb₄Br₆". Journal of Solid State Chemistry. 98 (1): 133–136. Bibcode:1992JSSCh..98..133S. doi:10.1016/0022-4596(92)90078-A.
^ Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 13. ISBN 978-0-412-30120-9.
^ ^a ^b Kheit, Messaoud; Merazka, Soumia; Kars, Mohammed; Gómez-Herrero, Adrian; Roisnel, Thierry; Sidoumou, Mohamed (2022). "Etude expérimentale et théorique d'un nouveau composé halogène pnicture Hg₁₂Sb₆(Br_5,186I_6,814)". Comptes Rendus. Chimie. 25 (G1): 189–203. doi:10.5802/crchim.191. ISSN 1878-1543. S2CID 251548809.
^ Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Ke-Feng; Guo, Guo-Cong; Li, Shao-Zhen; Liu, Jun-Ming (October 2014). "Large and Fast Single-Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host-Guest Interactions". Chemistry: An Asian Journal. 9 (10): 2872–2879. doi:10.1002/asia.201402572. PMID 25110860.
^ Schlirf, J.; Deiseroth, H. J. (January 2007). "Sb2Hg3GaBr4: A New Supramolecular Framework Structure with [Sb2Hg4/2]±0 Building Blocks Isosteric to Distibane". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (1): 47–50. doi:10.1002/zaac.200600180.
^ Zou, Jian-Ping; Guo, Sheng-Ping; Jiang, Xiao-Ming; Liu, Guang-Ning; Guo, Guo-Cong; Huang, Jin-Shun (September 2009). "Synthesis, crystal and band structures, and optical properties of a new supramolecular complex: [Hg6Sb4](InBr6)Br". Solid State Sciences. 11 (9): 1717–1721. Bibcode:2009SSSci..11.1717Z. doi:10.1016/j.solidstatesciences.2009.05.021.
^ Beck, Johannes; Neisel, Udo (2001). "Polykationische Hg-Pnictid-Gerüste mit einer neuen Füllungsvariante in den Strukturen von Hg₃As₂TlCl₃ und Hg₃Sb₂TlBr₃". Zeitschrift für Anorganische und Allgemeine Chemie. 627 (8): 2016–2022. doi:10.1002/1521-3749(200108)627:8<2016::AID-ZAAC2016>3.0.CO;2-N.

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[1] Shevelkov, A. V.; Shatruk, M. M. (2001). "". Russian Chemical Bulletin. 50 (3): 337–352. doi:10.1023/a:1011351532249. S2CID 94548971.

[:0-2] Beck, Johannes; Hedderich, Sylvia; Neisel, Udo (November 2000). "Synthesis and Crystal Structures of Hg₆Sb₅Br₇, Hg₆As₄BiCl₇, and Hg₆Sb₄BiBr₇, Built of a Polycationic Mercury-Pnictide Framework with Trapped Anions". Journal of Solid State Chemistry. 154 (2): 350–355. Bibcode:2000JSSCh.154..350B. doi:10.1006/jssc.2000.8794.

[3] Menke, Heinz; von Schnering, Hans Georg (January 1973). "Die Käfigverbindungen Ge38A8X8mit A = P, As. Sb und X = Cl, Br, J". Zeitschrift für anorganische und allgemeine Chemie (in German). 395 (2–3): 223–238. doi:10.1002/zaac.19733950211. ISSN 0044-2313.

[4] L.N., Reshetova; A.V., Shevel'kov; B.A., Popovkin (1999). "Synthesis and crystal structure of Cd₂SbBr₂". Koordinatsionnaya Khimiya (in Russian). 25 (11). ISSN 0132-344X.

[5] Shevelkov, A.V.; Dikarev, E.V.; Popovkin, B.A. (May 1992). "The crystal structure of Hg₇Sb₄Br₆". Journal of Solid State Chemistry. 98 (1): 133–136. Bibcode:1992JSSCh..98..133S. doi:10.1016/0022-4596(92)90078-A.

[6] Macintyre, Jane E. (23 July 1992). Dictionary of Inorganic Compounds. CRC Press. p. 13. ISBN 978-0-412-30120-9.

[:1-7] Kheit, Messaoud; Merazka, Soumia; Kars, Mohammed; Gómez-Herrero, Adrian; Roisnel, Thierry; Sidoumou, Mohamed (2022). "Etude expérimentale et théorique d'un nouveau composé halogène pnicture Hg₁₂Sb₆(Br_5,186I_6,814)". Comptes Rendus. Chimie. 25 (G1): 189–203. doi:10.5802/crchim.191. ISSN 1878-1543. S2CID 251548809.

[8] Jiang, Xiao-Ming; Yan, Zhi-Bo; Liu, Dan; Wang, Ke-Feng; Guo, Guo-Cong; Li, Shao-Zhen; Liu, Jun-Ming (October 2014). "Large and Fast Single-Crystal Resistive Humidity Sensitivity of Metal Pnictide Halides Containing van der Waals Host-Guest Interactions". Chemistry: An Asian Journal. 9 (10): 2872–2879. doi:10.1002/asia.201402572. PMID 25110860.

[9] Schlirf, J.; Deiseroth, H. J. (January 2007). "Sb2Hg3GaBr4: A New Supramolecular Framework Structure with [Sb2Hg4/2]±0 Building Blocks Isosteric to Distibane". Zeitschrift für anorganische und allgemeine Chemie (in German). 633 (1): 47–50. doi:10.1002/zaac.200600180.

[10] Zou, Jian-Ping; Guo, Sheng-Ping; Jiang, Xiao-Ming; Liu, Guang-Ning; Guo, Guo-Cong; Huang, Jin-Shun (September 2009). "Synthesis, crystal and band structures, and optical properties of a new supramolecular complex: [Hg6Sb4](InBr6)Br". Solid State Sciences. 11 (9): 1717–1721. Bibcode:2009SSSci..11.1717Z. doi:10.1016/j.solidstatesciences.2009.05.021.

[11] Beck, Johannes; Neisel, Udo (2001). "Polykationische Hg-Pnictid-Gerüste mit einer neuen Füllungsvariante in den Strukturen von Hg₃As₂TlCl₃ und Hg₃Sb₂TlBr₃". Zeitschrift für Anorganische und Allgemeine Chemie. 627 (8): 2016–2022. doi:10.1002/1521-3749(200108)627:8<2016::AID-ZAAC2016>3.0.CO;2-N.

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