Perbromyl fluoride

Perbromyl fluoride
Names
	Other names Bromine fluoride trioxide
Identifiers
CAS Number	25251-03-0 ;
3D model (JSmol)	Interactive image;
PubChem CID	44233513;
	InChI InChI=1S/BrFO3/c2-1(3,4)5 Key: FHRGMUIQMATFDZ-UHFFFAOYSA-N;
	SMILES F(=O)(=O)=O;
Properties
Chemical formula	BrFO3
Molar mass	146.899 g·mol−1
Appearance	colorless gas
Melting point	−9 °C (16 °F; 264 K)
Solubility in water	reacts with water
Related compounds
Related compounds	Periodyl fluoride; Perchloryl fluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Perbromyl fluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrO₃F.^[1]^[2]

Synthesis

Synthesis if perbromyl fluoride is by the effect of antimony pentafluoride on a solution of potassium perbromate in hydrofluoric acid:^[3]

KBrO₄ + 2SbF₅ + 3HF → BrO₃F + K[SbF₆ + H[SbF₆•H₂O

Physical properties

Perbromyl fluoride forms a colorless gas that is stable in the absence of moisture.^[4]

Chemical properties

Perbromyl fluoride reacts with water:

BrO₃F + H₂O → HBrO₄ + HF

References

^ Johnson, Gerald K.; O'Hare, P. A. G.; Appelman, Evan H. (1972). "Perbromyl fluoride". 11 (4). NIST: 800–802. doi:10.1021/ic50110a028. Retrieved 5 June 2023. {{cite journal}}: Cite journal requires |journal= (help)
^ Appleman, Evan H.; Studier, Martin H. (July 1969). "Perbromyl fluoride". Journal of the American Chemical Society. 91 (16): 4561–4562. doi:10.1021/ja01044a049. ISSN 0002-7863. Retrieved 5 June 2023.
^ Steudel, Ralf (20 April 2011). Chemistry of the Non-Metals: With an Introduction to Atomic Structure and Chemical Bonding. Walter de Gruyter. p. 265. ISBN 978-3-11-083082-8. Retrieved 5 June 2023.
^ U. S. Atomic Energy Commission Division of Plans and Atomic Energy Research: Life and Physical Sciences, Reactor Development, Waste Management. U.S. Government Printing Office. 1970. p. 10. Retrieved 5 June 2023.

Zdroj:https://en.wikipedia.org?pojem=Perbromyl_fluoride
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[1] Johnson, Gerald K.; O'Hare, P. A. G.; Appelman, Evan H. (1972). "Perbromyl fluoride". 11 (4). NIST: 800–802. doi:10.1021/ic50110a028. Retrieved 5 June 2023. {{cite journal}}: Cite journal requires |journal= (help)

[2] Appleman, Evan H.; Studier, Martin H. (July 1969). "Perbromyl fluoride". Journal of the American Chemical Society. 91 (16): 4561–4562. doi:10.1021/ja01044a049. ISSN 0002-7863. Retrieved 5 June 2023.

[3] Steudel, Ralf (20 April 2011). Chemistry of the Non-Metals: With an Introduction to Atomic Structure and Chemical Bonding. Walter de Gruyter. p. 265. ISBN 978-3-11-083082-8. Retrieved 5 June 2023.

[4] U. S. Atomic Energy Commission Division of Plans and Atomic Energy Research: Life and Physical Sciences, Reactor Development, Waste Management. U.S. Government Printing Office. 1970. p. 10. Retrieved 5 June 2023.

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v t e Bromine compounds
Br(−I)	Br⁻ CH₃Br CH₂Br₂ CHBr₃ CBr₄ HBr C₃H₅Br
Br(−I,I)	Br₃⁻
Br(I)	BrCl BrF BrN₃ BrNO₃ Br₂O BrO⁻ NBr₃
Br(II)	BrO
Br(I,V)	Br₂O₃
Br(III)	BrF₃ BrO₂⁻
Br(IV)	BrO₂
Br(V)	BrF₅ Br₂O₅ BrO₃⁻ BrOF₃ BrO₂F
Br(VII)	BrO₄⁻ BrO₃F