Bromosyl trifluoride

Bromosyl trifluoride
Names
	Other names Bromine oxide trifluoride, bromosyltrifluoride
Identifiers
CAS Number	61519-37-7 ;
3D model (JSmol)	Interactive image;
PubChem CID	21732508;
	InChI InChI=1S/BrF3O/c2-1(3,4)5 Key: VPGKBABVAVJLLQ-UHFFFAOYSA-N;
	SMILES O=Br(F)(F)F;
Properties
Chemical formula	BrF3O
Molar mass	152.898 g·mol−1
Appearance	colorless liquid
Related compounds
Related compounds	Chlorosyl trifluoride; Iodosyl trifluoride
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Bromosyl trifluoride is an inorganic compound of bromine, fluorine, and oxygen with the chemical formula BrOF₃.^[1]^[2]

Synthesis

Synthesis of bromosyl trifluoride is by reaction of anhydrous HF with K[BrOF₄ at –78 °C.^[3]

HF + K[BrOF₄ → BrOF₃ + K[HF₂

Also it can be formed by a reaction of LiNO₃ with BrF₅.^[4]

Physical properties

Bromosyl trifluoride forms a colorless liquid at room temperature. It reacts with water.^[5]

Chemical properties

Bromosyl trifluoride is quite unstable and decomposes at room temperature:

2BrOF₃ → 2BrF₃ + O₂

References

^ Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties". Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN 1364-5447. Retrieved 24 May 2023.
^ "bromine trifluoride oxide". ChemSrc. Retrieved 24 May 2023.
^ Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 468. ISBN 978-0-12-352651-9. Retrieved 24 May 2023.
^ Ellern, Arkady; Boatz, Jerry A.; Christe, Karl O.; Drews, Thomas; Seppelt, Konrad (September 2002). "The Crystal Structures of ClF3O, BrF3O, and +−". Zeitschrift für Anorganische und Allgemeine Chemie (in German). 628 (9–10): 1991–1999. doi:10.1002/1521-3749(200209)628:9/10<1991::AID-ZAAC1991>3.0.CO;2-1. ISSN 0044-2313. S2CID 94064764.
^ Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. pp. 4–53. ISBN 978-1-4822-6097-7. Retrieved 24 May 2023.

Zdroj:https://en.wikipedia.org?pojem=Bromosyl_trifluoride
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[1] Gillespie, Ronald J.; Spekkens, Paul H. (1 January 1977). "Bromyl fluoride and bromosyl trifluoride: preparation and chemical and spectroscopic properties". Journal of the Chemical Society, Dalton Transactions (16): 1539–1546. doi:10.1039/DT9770001539. ISSN 1364-5447. Retrieved 24 May 2023.

[2] "bromine trifluoride oxide". ChemSrc. Retrieved 24 May 2023.

[3] Wiberg, Egon; Wiberg, Nils (2001). Inorganic Chemistry. Academic Press. p. 468. ISBN 978-0-12-352651-9. Retrieved 24 May 2023.

[4] Ellern, Arkady; Boatz, Jerry A.; Christe, Karl O.; Drews, Thomas; Seppelt, Konrad (September 2002). "The Crystal Structures of ClF3O, BrF3O, and +−". Zeitschrift für Anorganische und Allgemeine Chemie (in German). 628 (9–10): 1991–1999. doi:10.1002/1521-3749(200209)628:9/10<1991::AID-ZAAC1991>3.0.CO;2-1. ISSN 0044-2313. S2CID 94064764.

[5] Haynes, William M. (9 June 2015). CRC Handbook of Chemistry and Physics, 96th Edition. CRC Press. pp. 4–53. ISBN 978-1-4822-6097-7. Retrieved 24 May 2023.

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v t e Bromine compounds
Br(−I)	Br⁻ CH₃Br CH₂Br₂ CHBr₃ CBr₄ HBr C₃H₅Br
Br(−I,I)	Br₃⁻
Br(I)	BrCl BrF BrN₃ BrNO₃ Br₂O BrO⁻ NBr₃
Br(II)	BrO
Br(I,V)	Br₂O₃
Br(III)	BrF₃ BrO₂⁻
Br(IV)	BrO₂
Br(V)	BrF₅ Br₂O₅ BrO₃⁻ BrOF₃ BrO₂F
Br(VII)	BrO₄⁻ BrO₃F