Lead(II) selenate

Lead(II) selenate
Identifiers
CAS Number	7446-15-3 ;
3D model (JSmol)	Interactive image;
ECHA InfoCard	100.028.363
EC Number	231-199-4;
PubChem CID	53471519;
CompTox Dashboard (EPA)	DTXSID10883503 ;
	InChI InChI=1S/H2O4Se.Pb/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2 Key: PKMXSWXQNCMWNG-UHFFFAOYSA-L;
	SMILES .(=O)(=O);
Properties
Chemical formula	PbSeO4
Molar mass	350.16
Appearance	transparent solid
Density	6.37 g·cm−3
Solubility in water	130 mg/l at 25 °C
Solubility	Soluble in concentrated acids
Hazards
	GHS labelling:
Pictograms
Signal word	Warning
Hazard statements	H301, H330, H331, H360, H373, H410
Precautionary statements	P203, P260, P261, P264, P270, P271, P273, P280, P284, P301+P316, P304+P340, P316, P318, P319, P320, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions	lead(II) sulfate; lead(II) tellurate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Lead(II) selenate is a selenate of lead, with the chemical formula PbSeO₄.

Preparation

Lead(II) selenate can be obtained by reacting a mixture of lead(II,IV) oxide and selenium dioxide with hydrogen peroxide.^[5] Lead(II) selenate is poorly soluble in water and can also be obtained through precipitation:^[6]

Pb²⁺
+ SeO²⁻
₄ → PbSeO
₄↓

References

^ Effenberger, H.; Pertlik, F. (Jan 1986). "Four monazite type structures: comparison of SrCrO 4 , SrSeO 4 , PbCrO 4 (crocoite), and PbSeO 4". Zeitschrift für Kristallographie. 176 (1–2): 75–83. Bibcode:1986ZK....176...75E. doi:10.1524/zkri.1986.176.1-2.75. ISSN 0044-2968.
^ ^a ^b ^c Lead(II) selenate, 99.9% at AlfaAesar, accessed on {{{Datum}}} (PDF) (JavaScript required).^{[dead link]}
^ William M. Haynes (2016), 1, p. 71, at Google Books CRC Handbook of Chemistry and Physics (93 ed.), CRC Press, p. 71, ISBN 978-1-4398-8050-0 {{citation}}: Check |url= value (help)
^ "Lead selenate". pubchem.ncbi.nlm.nih.gov.
^ Effenberger, H.; Pertlik, F. (1986-10-01). "Four monazite type structures: comparison of SrCrO₄, SrSeO₄, PbCrO₄(crocoite), and PbSeO₄". Zeitschrift für Kristallographie - Crystalline Materials. 176 (1–2): 75–84. doi:10.1524/zkri.1986.176.12.75. ISSN 2196-7105. S2CID 101572453.
^ Selivanova, N. M.; Kapustinskii, A. F.; Zubova, G. A. (Feb 1959). "Thermochemical properties of sparingly soluble selenates and entropy of aqueous selenate ion". Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 8 (2): 174–180. doi:10.1007/bf00917358. ISSN 0568-5230.

Zdroj:https://en.wikipedia.org?pojem=Lead(II)_selenate
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[1] Effenberger, H.; Pertlik, F. (Jan 1986). "Four monazite type structures: comparison of SrCrO 4 , SrSeO 4 , PbCrO 4 (crocoite), and PbSeO 4". Zeitschrift für Kristallographie. 176 (1–2): 75–83. Bibcode:1986ZK....176...75E. doi:10.1524/zkri.1986.176.1-2.75. ISSN 0044-2968.

[Alfa-2] Lead(II) selenate, 99.9% at AlfaAesar, accessed on {{{Datum}}} (PDF) (JavaScript required).^{[dead link]}

[William_M._Haynes-3] William M. Haynes (2016), 1, p. 71, at Google Books CRC Handbook of Chemistry and Physics (93 ed.), CRC Press, p. 71, ISBN 978-1-4398-8050-0 {{citation}}: Check |url= value (help)

[4] "Lead selenate". pubchem.ncbi.nlm.nih.gov.

[5] Effenberger, H.; Pertlik, F. (1986-10-01). "Four monazite type structures: comparison of SrCrO₄, SrSeO₄, PbCrO₄(crocoite), and PbSeO₄". Zeitschrift für Kristallographie - Crystalline Materials. 176 (1–2): 75–84. doi:10.1524/zkri.1986.176.12.75. ISSN 2196-7105. S2CID 101572453.

[6] Selivanova, N. M.; Kapustinskii, A. F.; Zubova, G. A. (Feb 1959). "Thermochemical properties of sparingly soluble selenates and entropy of aqueous selenate ion". Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 8 (2): 174–180. doi:10.1007/bf00917358. ISSN 0568-5230.

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v t e Lead compounds
Pb(II)	Pb(BiO₃)₂ PbBr₂ Pb(C₅H₅)₂ Pb(C₂H₃O₂)₂ PbC₂O₄ PbC₃₂H₁₆N₈ PbCl₂ Pb(ClO₄)₂ PbCO₃ PbCrO₄ PbF₂ PbHAsO₄ PbI₂ Pb(C ₁₁H ₂₃COO) ₂ Pb(NO₃)₂ Pb(N₃)₂ PbO Pb(OH)₂ PbPo PbP₇ Pb₃(PO₄)₂ PbS Pb(SCN)₂ PbSe PbSO₄ PbSeO₄ PbTe PbTiO₃ PbGeO₃ C ₃₆H ₇₀PbO ₄ plumbite PbC₂ (hypothetical)
Pb(II,IV)	Pb₃O₄
Pb(IV)	Pb(C₂H₃O₂)₄ PbCl₄ PbF₄ PbH₄ PbO₂ PbS₂ plumbate Pb(OH)₄ (hypothetical)

Identifiers

CAS Number	7446-15-3^Y
3D model (JSmol)	Interactive image
ECHA InfoCard	100.028.363
EC Number	231-199-4
PubChem CID	53471519
CompTox Dashboard (EPA)	DTXSID10883503
InChI InChI=1S/H2O4Se.Pb/c1-5(2,3)4;/h(H2,1,2,3,4);/q;+2/p-2 Key: PKMXSWXQNCMWNG-UHFFFAOYSA-L
SMILES .(=O)(=O)
Properties
Chemical formula	PbSeO₄
Molar mass	350.16
Appearance	transparent solid^[1]^[2]
Density	6.37 g·cm⁻³^[2]
Solubility in water	130 mg/l at 25 °C^[3]
Solubility	Soluble in concentrated acids^[2]
Hazards
GHS labelling:^[4]
Pictograms
Signal word	Warning
Hazard statements	H301, H330, H331, H360, H373, H410
Precautionary statements	P203, P260, P261, P264, P270, P271, P273, P280, P284, P301+P316, P304+P340, P316, P318, P319, P320, P321, P330, P391, P403+P233, P405, P501
Related compounds
Other anions	lead(II) sulfate lead(II) tellurate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references