A | B | C | D | E | F | G | H | CH | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z | 0 | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9
Names | |
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Preferred IUPAC name
(Ethylsulfanyl)ethane | |
Other names
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Identifiers | |
3D model (JSmol)
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1696909 | |
ChEBI | |
ChEMBL | |
ChemSpider | |
ECHA InfoCard | 100.005.934 |
EC Number |
|
1915 | |
KEGG | |
PubChem CID
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RTECS number |
|
UNII | |
CompTox Dashboard (EPA)
|
|
| |
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Properties | |
(CH3CH2)2S | |
Molar mass | 90.18 g·mol−1 |
Appearance | Colorless liquid |
Odor | Unpleasant |
Density | 0.837 g/cm3 |
Melting point | −103.8 °C (−154.8 °F; 169.3 K) |
Boiling point | 92 °C (198 °F; 365 K) |
insoluble | |
Solubility in ethanol | miscible |
Solubility in diethyl ether | miscible |
−67.9·10−6 cm3/mol | |
Refractive index (nD)
|
1.44233 |
Hazards[1] | |
Occupational safety and health (OHS/OSH): | |
Main hazards
|
Skin and eye irritant. Highly flammable liquid and vapor |
GHS labelling: | |
Danger | |
H225, H315, H319 | |
P210, P233, P264, P280, P303+P361+P353, P370+P378 | |
NFPA 704 (fire diamond) | |
Flash point | −10 °C (14 °F; 263 K) |
Safety data sheet (SDS) | External MSDS |
Related compounds | |
Related thioethers
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|
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa).
|
Diethyl sulfide (British English: diethyl sulphide) is an organosulfur compound with the chemical formula (CH3CH2)2S. It is a colorless, malodorous liquid. Although a common thioether, it has few applications.
Preparation
Diethyl sulfide is a by-product of the commercial production of ethanethiol, which is prepared by the reaction of ethylene with hydrogen sulfide over an alumina-based catalyst. The amount of diethyl sulfide produced can be controlled by varying the ratio of hydrogen sulfide to ethylene.
Occurrence
Diethyl sulfide has been found to be a constituent of the odor of durian fruit[2] and as a constituent found in volatiles from potatoes.[3]
Reactions
Diethyl sulfide is a Lewis base, classified as a soft ligand (see also ECW model). Its relative donor strength toward a series of acids, versus other Lewis bases, can be illustrated by C-B plots.[4][5]
With bromine, it forms a salt called diethylbromosulfonium bromide:[6]
- (CH3CH2)2S + Br2 → [(CH3CH2)2SBr+Br−
A typical coordination complex is cis-PtCl2(S(CH2CH3)2)2.
References
- ^ "GESTIS-Stoffdatenbank". gestis.dguv.de (in German).
- ^ Baldry, Jane; J. Dougan; G. E. Howard (1972). "Volatile Flavouring Constituents of Durian". Phytochemistry. 11 (6): 2081–2084. Bibcode:1972PChem..11.2081B. doi:10.1016/s0031-9422(00)90176-6.
- ^ Gumbmann, M. R.; H. K. Burr (1964). "Food Flavors and Odors, Volatile Sulfur Compounds in Potatoes". Journal of Agricultural and Food Chemistry. 12 (5): 404–408. doi:10.1021/jf60135a004.
- ^ Laurence, C. and Gal, J-F. Lewis Basicity and Affinity Scales, Data and Measurement, (Wiley 2010) pp 50-51 ISBN 978-0-470-74957-9
- ^ Cramer, R. E.; Bopp, T. T. (1977). "Graphical display of the enthalpies of adduct formation for Lewis acids and bases". Journal of Chemical Education. 54: 612–613. doi:10.1021/ed054p612. The plots shown in this paper used older parameters. Improved E&C parameters are listed in ECW model.
- ^ Scott A. Snyder, Daniel S. Treitler (2011). "Synthesis of Et2SBrSbCl5Br and Its Use in Biomimetic Brominative Polyene Cyclizations". Organic Syntheses. 88: 54. doi:10.15227/orgsyn.088.0054.
- ^ C.Hansson (2007). "cis-Dichloridobis(diethyl sulfide-κS)platinum(II) at 295 and 150 K". Acta Crystallographica Section C. 63 (Pt 8): m361-3. doi:10.1107/S0108270107030417. PMID 17675684.
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