Light–matter interaction
Low-energy phenomena:
Photoelectric effect
Mid-energy phenomena:
Thomson scattering
Compton scattering
High-energy phenomena:
Pair production
Photodisintegration
Photofission
v t e

Compton scattering (or the Compton effect) is the quantum theory of high frequency photons scattering following an interaction with a charged particle, usually an electron. Specifically, when the photon hits electrons, it releases loosely bound electrons from the outer valence shells of atoms or molecules.

The effect was discovered in 1923 by Arthur Holly Compton while researching the scattering of X-rays by light elements, and earned him the Nobel Prize for Physics in 1927. The Compton effect significantly deviated from dominating classical theories, using both special relativity and quantum mechanics to explain the interaction between high frequency photons and charged particles.

Photons can interact with matter at the atomic level (e.g. photoelectric effect and Rayleigh scattering), at the nucleus, or with just an electron. Pair production and the Compton effect occur at the level of the electron.^[1] When a high frequency photon scatters due to an interaction with a charged particle, there is a decrease in the energy of the photon (and thus, an increase in its wavelength.) This is the Compton effect. Because of conservation of energy the lost energy from the photon is transferred to the recoiling particle (such an electron would be called a "Compton Recoil electron").

This implies that if the recoiling particle initially carried more energy than the photon, the reverse would occur. This is known as inverse Compton scattering, in which the scattered photon increases in energy.

Introduction

In Compton's original experiment (see Fig. 1), the energy of the X ray photon (≈17 keV) was significantly larger than the binding energy of the atomic electron, so the electrons could be treated as being free after scattering. The amount by which the light's wavelength changes is called the Compton shift. Although nucleus Compton scattering exists,^[2] Compton scattering usually refers to the interaction involving only the electrons of an atom. The Compton effect was observed by Arthur Holly Compton in 1923 at Washington University in St. Louis and further verified by his graduate student Y. H. Woo in the years following. Compton was awarded the 1927 Nobel Prize in Physics for the discovery.

The effect is significant because it demonstrates that light cannot be explained purely as a wave phenomenon.^[3] Thomson scattering, the classical theory of an electromagnetic wave scattered by charged particles, cannot explain shifts in wavelength at low intensity: classically, light of sufficient intensity for the electric field to accelerate a charged particle to a relativistic speed will cause radiation-pressure recoil and an associated Doppler shift of the scattered light,^[4] but the effect would become arbitrarily small at sufficiently low light intensities regardless of wavelength. Thus, if we are to explain low-intensity Compton scattering, light must behave as if it consists of particles. Or the assumption that the electron can be treated as free is invalid resulting in the effectively infinite electron mass equal to the nuclear mass (see e.g. the comment below on elastic scattering of X-rays being from that effect). Compton's experiment convinced physicists that light can be treated as a stream of particle-like objects (quanta called photons), whose energy is proportional to the light wave's frequency.

As shown in Fig. 2, the interaction between an electron and a photon results in the electron being given part of the energy (making it recoil), and a photon of the remaining energy being emitted in a different direction from the original, so that the overall momentum of the system is also conserved. If the scattered photon still has enough energy, the process may be repeated. In this scenario, the electron is treated as free or loosely bound. Experimental verification of momentum conservation in individual Compton scattering processes by Bothe and Geiger as well as by Compton and Simon has been important in disproving the BKS theory.

Compton scattering is commonly described as inelastic scattering, because the energy in the scattered photon is less than the energy of the incident photon.^[5][6] Energy of the incident photon is transferred to the recoil particle, but only as kinetic energy. The electron gains no internal energy, respective masses remain the same, the mark of an elastic collision. From this perspective, Compton scattering could be considered elastic because the internal state of the electron does not change during the scattering process. Whether Compton scattering is considered elastic or inelastic depends on the specific definition of these terms being used.

Compton scattering is one of four competing processes when photons interact with matter. At energies of a few eV to a few keV, corresponding to visible light through soft X-rays, a photon can be completely absorbed and its energy can eject an electron from its host atom, a process known as the photoelectric effect. High-energy photons of 1.022 MeV and above may bombard the nucleus and cause an electron and a positron to be formed, a process called pair production; even-higher-energy photons (beyond a threshold energy of at least 1.670 MeV, depending on the nuclei involved), can eject a nucleon or alpha particle from the nucleus in a process called photodisintegration. Compton scattering is the most important interaction in the intervening energy region, at photon energies greater than those typical of the photoelectric effect but less than the pair-production threshold.

Description of the phenomenon

By the early 20th century, research into the interaction of X-rays with matter was well under way. It was observed that when X-rays of a known wavelength interact with atoms, the X-rays are scattered through an angle ${\displaystyle \theta }$ and emerge at a different wavelength related to ${\displaystyle \theta }$. Although classical electromagnetism predicted that the wavelength of scattered rays should be equal to the initial wavelength,^[7] multiple experiments had found that the wavelength of the scattered rays was longer (corresponding to lower energy) than the initial wavelength.^[7]

In 1923, Compton published a paper in the Physical Review that explained the X-ray shift by attributing particle-like momentum to light quanta (Einstein had proposed light quanta in 1905 in explaining the photo-electric effect, but Compton did not build on Einstein's work). The energy of light quanta depends only on the frequency of the light. In his paper, Compton derived the mathematical relationship between the shift in wavelength and the scattering angle of the X-rays by assuming that each scattered X-ray photon interacted with only one electron. His paper concludes by reporting on experiments which verified his derived relation:

$${\displaystyle \lambda '-\lambda ={\frac {h}{m_{e}c}}(1-\cos {\theta }),}$$

• ${\displaystyle \lambda }$ is the initial wavelength,
• ${\displaystyle \lambda '}$ is the wavelength after scattering,
• ${\displaystyle h}$ is the Planck constant,
• ${\displaystyle m_{e}}$ is the electron rest mass,
• ${\displaystyle c}$ is the speed of light, and
• ${\displaystyle \theta }$ is the scattering angle.

The quantity h/m_ec is known as the Compton wavelength of the electron; it is equal to 2.43×10⁻¹² m. The wavelength shift λ′ − λ is at least zero (for θ = 0°) and at most twice the Compton wavelength of the electron (for θ = 180°).

Compton found that some X-rays experienced no wavelength shift despite being scattered through large angles; in each of these cases the photon failed to eject an electron.^[7] Thus the magnitude of the shift is related not to the Compton wavelength of the electron, but to the Compton wavelength of the entire atom, which can be upwards of 10000 times smaller. This is known as "coherent" scattering off the entire atom since the atom remains intact, gaining no internal excitation.

In Compton's original experiments the wavelength shift given above was the directly measurable observable. In modern experiments it is conventional to measure the energies, not the wavelengths, of the scattered photons. For a given incident energy ${\displaystyle E_{\gamma }=hc/\lambda }$, the outgoing final-state photon energy, ${\displaystyle E_{\gamma ^{\prime }}}$, is given by

$${\displaystyle E_{\gamma ^{\prime }}={\frac {E_{\gamma }}{1+(E_{\gamma }/m_{e}c^{2})(1-\cos \theta )}}.}$$

Derivation of the scattering formula

A photon γ with wavelength λ collides with an electron e in an atom, which is treated as being at rest. The collision causes the electron to recoil, and a new photon γ' with wavelength λ' emerges at angle θ from the photon's incoming path. Let e' denote the electron after the collision. Compton allowed for the possibility that the interaction would sometimes accelerate the electron to speeds sufficiently close to the velocity of light as to require the application of Einstein's special relativity theory to properly describe its energy and momentum.

At the conclusion of Compton's 1923 paper, he reported results of experiments confirming the predictions of his scattering formula, thus supporting the assumption that photons carry momentum as well as quantized energy. At the start of his derivation, he had postulated an expression for the momentum of a photon from equating Einstein's already established mass-energy relationship of ${\displaystyle E=mc^{2}}$ to the quantized photon energies of ${\displaystyle hf}$, which Einstein had separately postulated. If ${\displaystyle mc^{2}=hf}$, the equivalent photon mass must be ${\displaystyle hf/c^{2}}$. The photon's momentum is then simply this effective mass times the photon's frame-invariant velocity c. For a photon, its momentum ${\displaystyle p=hf/c}$, and thus hf can be substituted for pc for all photon momentum terms which arise in course of the derivation below. The derivation which appears in Compton's paper is more terse, but follows the same logic in the same sequence as the following derivation.

The conservation of energy ${\displaystyle E}$ merely equates the sum of energies before and after scattering.

${\displaystyle E_{\gamma }+E_{e}=E_{\gamma '}+E_{e'}.}$

Compton postulated that photons carry momentum;^[7] thus from the conservation of momentum, the momenta of the particles should be similarly related by

${\displaystyle \mathbf {p} _{\gamma }=\mathbf {p} _{\gamma '}+\mathbf {p} _{e'},}$

in which (${\displaystyle {p_{e}}}$) is omitted on the assumption it is effectively zero.

The photon energies are related to the frequencies by

${\displaystyle E_{\gamma }=hf}$

${\displaystyle E_{\gamma '}=hf'}$

where h is Planck's constant.

Before the scattering event, the electron is treated as sufficiently close to being at rest that its total energy consists entirely of the mass-energy equivalence of its (rest) mass ${\displaystyle m_{e}}$,

${\displaystyle E_{e}=m_{e}c^{2}.}$

After scattering, the possibility that the electron might be accelerated to a significant fraction of the speed of light, requires that its total energy be represented using the relativistic energy–momentum relation

${\displaystyle E_{e'}={\sqrt {(p_{e'}c)^{2}+(m_{e}c^{2})^{2}}}~.}$

Substituting these quantities into the expression for the conservation of energy gives

${\displaystyle hf+m_{e}c^{2}=hf'+{\sqrt {(p_{e'}c)^{2}+(m_{e}c^{2})^{2}}}.}$

This expression can be used to find the magnitude of the momentum of the scattered electron,