Thorium-231 - Biblioteka.sk

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Thorium-231
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Isotopes of thorium (90Th)
Main isotopes[1] Decay
abun­dance half-life (t1/2) mode pro­duct
227Th trace 18.68 d α 223Ra
228Th trace 1.9116 y α 224Ra
229Th trace 7917 y[2] α 225Ra
230Th 0.02% 75400 y α 226Ra
231Th trace 25.5 h β 231Pa
232Th 100% 1.405×1010 y α 228Ra
233Th trace 21.83 min β 233Pa
234Th trace 24.1 d β 234Pa
Standard atomic weight Ar°(Th)

Thorium (90Th) has seven naturally occurring isotopes but none are stable. One isotope, 232Th, is relatively stable, with a half-life of 1.405×1010 years, considerably longer than the age of the Earth, and even slightly longer than the generally accepted age of the universe. This isotope makes up nearly all natural thorium, so thorium was considered to be mononuclidic. However, in 2013, IUPAC reclassified thorium as binuclidic, due to large amounts of 230Th in deep seawater. Thorium has a characteristic terrestrial isotopic composition and thus a standard atomic weight can be given.

Thirty-one radioisotopes have been characterized, with the most stable being 232Th, 230Th with a half-life of 75,380 years, 229Th with a half-life of 7,917 years,[2] and 228Th with a half-life of 1.92 years. All of the remaining radioactive isotopes have half-lives that are less than thirty days and the majority of these have half-lives that are less than ten minutes. One isotope, 229Th, has a nuclear isomer (or metastable state) with a remarkably low excitation energy,[5] recently measured to be 8.28 ± 0.17 eV.[6] It has been proposed to perform laser spectroscopy of the 229Th nucleus and use the low-energy transition for the development of a nuclear clock of extremely high accuracy.[7][8]

The known isotopes of thorium range in mass number from 207[9] to 238.

List of isotopes

Nuclide
[n 1]
Historic
name
Z N Isotopic mass (Da)
[n 2][n 3]
Half-life
[n 4]
Decay
mode

[n 5]
Daughter
isotope

[n 6]
Spin and
parity
[n 7][n 8]
Natural abundance (mole fraction)
Excitation energy Normal proportion Range of variation
207Th[9] 90 117 9.7(+46.6−4.4) ms α 203Ra
208Th[10] 90 118 208.01791(4) 1.7(+1.7-0.6) ms α 204Ra 0+
209Th[11] 90 119 209.01772(11) 7(5) ms
α 205Ra 5/2−#
210Th 90 120 210.015075(27) 17(11) ms
α 206Ra 0+
β+ (rare) 210Ac
211Th 90 121 211.01493(8) 48(20) ms
α 207Ra 5/2−#
β+ (rare) 211Ac
212Th 90 122 212.01298(2) 36(15) ms
α (99.7%) 208Ra 0+
β+ (.3%) 212Ac
213Th 90 123 213.01301(8) 140(25) ms α 209Ra 5/2−#
β+ (rare) 213Ac
214Th 90 124 214.011500(18) 100(25) ms α 210Ra 0+
215Th 90 125 215.011730(29) 1.2(2) s α 211Ra (1/2−)
216Th 90 126 216.011062(14) 26.8(3) ms α (99.99%) 212Ra 0+
β+ (.006%) 216Ac
216m1Th 2042(13) keV 137(4) μs (8+)
216m2Th 2637(20) keV 615(55) ns (11−)
217Th 90 127 217.013114(22) 240(5) μs α 213Ra (9/2+)
218Th 90 128 218.013284(14) 109(13) ns α 214Ra 0+
219Th 90 129 219.01554(5) 1.05(3) μs α[n 9] 215Ra 9/2+#
220Th 90 130 220.015748(24) 9.7(6) μs α[n 10] 216Ra 0+
221Th 90 131 221.018184(10) 1.73(3) ms α 217Ra (7/2+)
222Th 90 132 222.018468(13) 2.237(13) ms α[n 11] 218Ra 0+
223Th 90 133 223.020811(10) 0.60(2) s α 219Ra (5/2)+
224Th 90 134 224.021467(12) 1.05(2) s α 220Ra 0+
CD (rare) 208Pb
16O
225Th 90 135 225.023951(5) 8.72(4) min α (90%) 221Ra (3/2)+
EC (10%) 225Ac
226Th 90 136 226.024903(5) 30.57(10) min α 222Ra 0+
227Th Radioactinium 90 137 227.0277041(27) 18.68(9) d α 223Ra 1/2+ Trace[n 12]
228Th Radiothorium 90 138 228.0287411(24) 1.9116(16) y α 224Ra 0+ Trace[n 13]
CD (1.3×10−11%) 208Pb
20O
229Th 90 Zdroj:https://en.wikipedia.org?pojem=Thorium-231
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