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Names | |
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IUPAC name
Sodium hexanitritocobaltate(III)
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Other names
Sodium cobaltinitrite
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Identifiers | |
3D model (JSmol)
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ChemSpider | |
ECHA InfoCard | 100.033.692 |
EC Number |
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PubChem CID
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UNII | |
CompTox Dashboard (EPA)
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Properties | |
Na3[Co(NO2)6 | |
Molar mass | 403.933 g·mol−1 |
Appearance | Yellow crystals |
Density | 2.565 g/cm3 |
Hazards | |
GHS labelling:[1] | |
Danger | |
H272, H315, H317, H319, H334, H335, H351 | |
Safety data sheet (SDS) | JT Baker MSDS |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa).
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Sodium hexanitritocobaltate(III) is inorganic compound with the formula Na3[Co(NO2)6. The anion of this yellow-coloured salt consists of the transition metal nitrite complex [Co(NO2)63−. It was a reagent for the qualitative test for potassium and ammonium ions.[2]
Synthesis and reactions
The compound is prepared by oxidation of cobalt(II) salts in the presence of sodium nitrite:[3]
- 4 [Co(H2O)6(NO3)2 + O2 + 24 NaNO2 → 4 Na3[Co(NO2)6 + 8 NaNO3 + 4 NaOH + 22 H2O
Application for analysis of potassium
Although the sodium cobaltinitrite is soluble in water, it forms the basis of a quantitative determination of potassium, thallium, and ammonium ions. Under the recommended reaction conditions the insoluble double salt, K2Na[Co(NO2)6·H2O is precipitated and weighed.[4][page needed] In geochemical analysis, sodium cobaltinitrite is used to distinguish alkali feldspars from plagioclase feldspars in thin section.[5]
See also
References
- ^ "C&L Inventory". echa.europa.eu.
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
- ^ Glemser, O. (1963). "Sodium Hexanitritocobaltate(III)". In Brauer, G. (ed.). Handbook of Preparative Inorganic Chemistry. Vol. 1 (2nd ed.). New York, NY: Academic Press. p. 1541.
- ^ Vogel, A. I. (1951). Quantitative Inorganic Analysis (2nd ed.). Longmans Green and Co.
- ^ Bailey, E. H.; Stevens, R. E. (1960). "Selective staining of K-feldspar and plagioclase on rock slabs and thin sections". American Mineralogist. 45: 1020–1025. ISSN 1945-3027.
- ^ Brian N. Figgis; Alexandre N. Soboleva (2001). "Na3Co(NO2)6 at 293 and 10 K". Acta Crystallographica Section C. 57 (Pt 8): 885–886. doi:10.1107/S0108270101007995. PMID 11498599.
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