Lanthanum(III) iodate

Lanthanum(III) iodate
Identifiers
CAS Number	13870-19-4 [echa];
3D model (JSmol)	Interactive image;
ChemSpider	20082411 ;
ECHA InfoCard	100.034.187
EC Number	237-621-3;
PubChem CID	15794045;
CompTox Dashboard (EPA)	DTXSID70160761 ;
	InChI InChI=1S/3HIO3.La/c32-1(3)4;/h3(H,2,3,4);/q;;;+3/p-3 Key: BULVJAIIOVREOT-UHFFFAOYSA-K;
	SMILES I(=O)=O.I(=O)=O.I(=O)=O.;
Properties
Chemical formula	La(IO3)3
Molar mass	663.617
Appearance	colourless crystals
Solubility in water	1.07×10-3mol·L-1
Related compounds
Other anions	lanthanum(III) nitrate; lanthanum(III) oxide
Other cations	cerium(III) iodate
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references

Lanthanum(III) iodate is an inorganic compound with the chemical formula La(IO₃)₃.

Preparation

Lanthanum(III) iodate can be obtained by reacting a La³⁺ salt with potassium iodate or ammonium iodate and precipitating it:^[1]

La³⁺ + 3 IO₃⁻ → La(IO₃)₃↓

Properties

Lanthanum(III) iodate can disproportionate and decompose to a periodate when heated:^[2]

10 La(IO₃)₃ → 2 La₅(IO₆)₃ + 12 I₂↑ + 27 O₂↑

References

^ ^a ^b 《无机化学丛书》. 第七卷钪稀土元素. 易宪武等主编. 科学出版社. P_184~185. 13. 卤素含氧酸盐
^ K. Nassau, J.W. Shiever, B.E. Prescott (Jun 1975). "Transition metal iodates. VI. Preparation and characterization of the larger lanthanide iodates". Journal of Solid State Chemistry. 14 (2): 122–132. Bibcode:1975JSSCh..14..122N. doi:10.1016/0022-4596(75)90002-X. Archived from the original on 2018-07-01. Retrieved 2020-05-29.{{cite journal}}: CS1 maint: multiple names: authors list (link)

Zdroj:https://en.wikipedia.org?pojem=Lanthanum(III)_iodate
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[wj-1] 《无机化学丛书》. 第七卷钪稀土元素. 易宪武等主编. 科学出版社. P_184~185. 13. 卤素含氧酸盐

[2] K. Nassau, J.W. Shiever, B.E. Prescott (Jun 1975). "Transition metal iodates. VI. Preparation and characterization of the larger lanthanide iodates". Journal of Solid State Chemistry. 14 (2): 122–132. Bibcode:1975JSSCh..14..122N. doi:10.1016/0022-4596(75)90002-X. Archived from the original on 2018-07-01. Retrieved 2020-05-29.{{cite journal}}: CS1 maint: multiple names: authors list (link)

[1]

[2]

Identifiers

CAS Number	13870-19-4^Y[echa]
3D model (JSmol)	Interactive image
ChemSpider	20082411^N
ECHA InfoCard	100.034.187
EC Number	237-621-3
PubChem CID	15794045
CompTox Dashboard (EPA)	DTXSID70160761
InChI InChI=1S/3HIO3.La/c32-1(3)4;/h3(H,2,3,4);/q;;;+3/p-3 Key: BULVJAIIOVREOT-UHFFFAOYSA-K
SMILES I(=O)=O.I(=O)=O.I(=O)=O.
Properties
Chemical formula	La(IO₃)₃
Molar mass	663.617
Appearance	colourless crystals
Solubility in water	1.07×10^-3mol·L^-1^[1]
Related compounds
Other anions	lanthanum(III) nitrate lanthanum(III) oxide
Other cations	cerium(III) iodate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C , 100 kPa). Infobox references