Isotopes of cadmium - Biblioteka.sk

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Isotopes of cadmium
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Isotopes of cadmium (48Cd)
Main isotopes[1] Decay
abun­dance half-life (t1/2) mode pro­duct
106Cd 1.25% stable
107Cd synth 6.5 h ε 107Ag
108Cd 0.89% stable
109Cd synth 462.6 d ε 109Ag
110Cd 12.5% stable
111Cd 12.8% stable
112Cd 24.1% stable
113Cd 12.2% 8.04×1015 y β 113In
113mCd synth 14.1 y β 113In
IT 113Cd
114Cd 28.8% stable
115Cd synth 53.46 h β 115In
116Cd 7.51% 2.8×1019 y ββ 116Sn
Standard atomic weight Ar°(Cd)

Naturally occurring cadmium (48Cd) is composed of 8 isotopes. For two of them, natural radioactivity was observed, and three others are predicted to be radioactive but their decays have not been observed, due to extremely long half-lives. The two natural radioactive isotopes are 113Cd (beta decay, half-life is 8.04 × 1015 years) and 116Cd (two-neutrino double beta decay, half-life is 2.8 × 1019 years). The other three are 106Cd, 108Cd (double electron capture), and 114Cd (double beta decay); only lower limits on their half-life times have been set. Three isotopes—110Cd, 111Cd, and 112Cd—are theoretically stable. Among the isotopes absent in natural cadmium, the most long-lived are 109Cd with a half-life of 462.6 days, and 115Cd with a half-life of 53.46 hours. All of the remaining radioactive isotopes have half-lives that are less than 2.5 hours and the majority of these have half-lives that are less than 5 minutes. This element also has 12 known meta states, with the most stable being 113mCd (t1/2 14.1 years), 115mCd (t1/2 44.6 days) and 117mCd (t1/2 3.36 hours).

The known isotopes of cadmium range in atomic mass from 94.950 u (95Cd) to 131.946 u (132Cd). The primary decay mode before the second most abundant stable isotope, 112Cd, is electron capture and the primary modes after are beta emission and electron capture. The primary decay product before 112Cd is element 47 (silver) and the primary product after is element 49 (indium).

A 2021 study has shown at high ionic strengths, Cd isotope fractionation mainly depends on its complexation with carboxylic sites. At low ionic strengths, nonspecific Cd binding induced by electrostatic attractions plays a dominant role and promotes Cd isotope fractionation during complexation.[4]

List of isotopes

Zdroj:https://en.wikipedia.org?pojem=Isotopes_of_cadmium
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Nuclide
[n 1]
Z N Isotopic mass (Da)
[n 2][n 3]
Half-life
[n 4]
Decay
mode

[n 5]
Daughter
isotope

[n 6][n 7]
Spin and
parity
[n 8][n 9]
Natural abundance (mole fraction)
Excitation energy[n 9] Normal proportion Range of variation
95Cd 48 47 94.94987(64)# 5# ms 9/2+#
96Cd 48 48 95.93977(54)# 1# s β+ 96Ag 0+
97Cd 48 49 96.93494(43)# 2.8(6) s β+ (>99.9%) 97Ag 9/2+#
β+, p (<.1%) 96Pd
98Cd 48 50 97.92740(8) 9.2(3) s β+ (99.975%) 98Ag 0+
β+, p (.025%) 97Ag
98mCd 2427.5(6) keV 190(20) ns 8+#
99Cd 48 51 98.92501(22)# 16(3) s β+ (99.78%) 99Ag (5/2+)
β+, p (.21%) 98Pd
β+, α (10−4%) 95Rh
100Cd 48 52 99.92029(10) 49.1(5) s β+ 100Ag 0+
101Cd 48 53 100.91868(16) 1.36(5) min β+ 101Ag (5/2+)
102Cd 48 54 101.91446(3) 5.5(5) min β+ 102Ag 0+
103Cd 48 55 102.913419(17) 7.3(1) min β+ 103Ag 5/2+
104Cd 48 56 103.909849(10) 57.7(10) min β+ 104Ag 0+
105Cd 48 57 104.909468(12) 55.5(4) min β+ 105Ag 5/2+
106Cd 48 58 105.906459(6) Observationally Stable[n 10] 0+ 0.0125(6)
107Cd 48 59 106.906618(6) 6.50(2) h β+ 107mAg 5/2+
108Cd 48 60 107.904184(6) Observationally Stable[n 11] 0+ 0.0089(3)
109Cd 48 61 108.904982(4) 461.4(12) d EC 109Ag 5/2+
109m1Cd 59.6(4) keV 12(2) μs 1/2+
109m2Cd 463.0(5) keV 10.9(5) μs 11/2
110Cd 48 62 109.9030021(29) Stable 0+ 0.1249(18)
111Cd[n 12] 48 63 110.9041781(29) Stable 1/2+ 0.1280(12)
111mCd 396.214(21) keV 48.50(9) min IT 111Cd 11/2−
112Cd[n 12] 48 64 111.9027578(29) Stable 0+ 0.2413(21)
113Cd[n 12][n 13] 48 65 112.9044017(29) 8.04(5)×1015 y β 113In 1/2+ 0.1222(12)
113mCd[n 12] 263.54(3) keV 14.1(5) y β (99.86%) 113In 11/2−
IT (.139%) 113Cd
114Cd[n 12] 48 66 113.9033585(29) Observationally Stable[n 14] 0+ 0.2873(42)
115Cd[n 12] 48 67 114.9054310(29) 53.46(5) h β 115mIn 1/2+
115mCd 181.0(5) keV 44.56(24) d β 115mIn (11/2)−
116Cd[n 12][n 13] 48 68 115.904756(3) 2.8(2)×1019 y ββ 116Sn 0+ 0.0749(18)
117Cd 48 69 116.907219(4) 2.49(4) h β 117mIn 1/2+
117mCd 136.4(2) keV 3.36(5) h β 117mIn (11/2)−
118Cd 48 70 117.906915(22) 50.3(2) min β 118In 0+
119Cd 48 71 118.90992(9) 2.69(2) min β 119mIn (3/2+)
119mCd 146.54(11) keV 2.20(2) min β 119mIn